『Abstract
Experiments on dissolution kinetics of galena were performed
in 1 mol l-1 NaCl solutions at pH 0.43-2.45 and 25-75℃.
When the dissolution reaction is far from equilibrium, a linear
relation exits between the dissolution rate, r, and the H+
ion activity, [H+]. The rate law for galena dissolution
is given by the following equation: r = k [H+]. With
respect to H+, the dissolution reaction is in the first
order. The apparent rate constant, k, has values of 2.34×10-7
mol m-2 s-1 at 25℃, 1.38×10-6
mol m-2 s-1 at 50℃, and 7.08×10-6
mol m-2 s-1 at 75℃. The activation energy
of dissolution reaction is 43.54 kJ mol-1. The mechanism
of dissolution is suggested to be surface chemical reaction, and
the rate determining step is the dissociation of the Pb-S bond
of the surface complex, which releases Pb2+ into the
solution.』
1. Introduction
2. Experimental methods
3. Experimental results
4. Discussion
4.1. Rate law
4.2. Reaction mechanism
5. Conclusion
Acknowledgements
References