Zhang et al.(2004)による〔『Dissolution kinetics of galena in acid NaCl solutions at 25−75℃』(835p)から〕

『25〜75℃の酸性NaCl溶液における方鉛鉱の溶解カイネティックス』


Abstract
 Experiments on dissolution kinetics of galena were performed in 1 mol l-1 NaCl solutions at pH 0.43-2.45 and 25-75℃. When the dissolution reaction is far from equilibrium, a linear relation exits between the dissolution rate, r, and the H+ ion activity, [H+]. The rate law for galena dissolution is given by the following equation: r = k [H+]. With respect to H+, the dissolution reaction is in the first order. The apparent rate constant, k, has values of 2.34×10-7 mol m-2 s-1 at 25℃, 1.38×10-6 mol m-2 s-1 at 50℃, and 7.08×10-6 mol m-2 s-1 at 75℃. The activation energy of dissolution reaction is 43.54 kJ mol-1. The mechanism of dissolution is suggested to be surface chemical reaction, and the rate determining step is the dissociation of the Pb-S bond of the surface complex, which releases Pb2+ into the solution.』

1. Introduction
2. Experimental methods
3. Experimental results
4. Discussion
 4.1. Rate law
 4.2. Reaction mechanism
5. Conclusion
Acknowledgements
References



戻る